METHOXYETHYLMERCURIC ACETATE

Editor's Note: This material is not listed in the Emergency Response Guidebook. Based on the material's physical and chemical properties, toxicity, or chemical group, a guide has been assigned. For additional technical information, contact one of the emergency response telephone numbers listed under Public Safety Measures.

MOLECULAR FORMULA

C5-H10-Hg-O3

ERG GUIDE NUMBER

151-SUBSTANCES - TOXIC (NON-COMBUSTIBLE)

SYNONYM REFERENCE

(RTECS , 1990; EPA, 1985)

USES/FORMS/SOURCES

USES

It is used as a fungicide and disinfectant in treating seeds (EPA, 1985; Sax & Lewis, 1987). Most alkyl mercury fungicides have been virtually prohibited from being used in the USA (Morgan, 1989).

FORMS

Methoxyethylmercuric acetate is an alkyl mercury compound which occurs as a white crystalline solid.

-CLINICAL EFFECTS

GENERAL CLINICAL EFFECTS

Little is known about the acute or chronic effects of methoxyethylmercuric acetate in humans. It can cause systemic effects through dermal exposure. Animal studies indicate that it can cause renal damage in a similar manner to inorganic mercury. Therefore this review is based on clinical effects of both organic and inorganic mercurials.

Mercury compounds can be absorbed by all routes of exposure. The principal concerns from acute poisoning are sudden, profound circulatory collapse with tachycardia, hypotension and peripheral vasoconstriction, vomiting, and bloody diarrhea. Renal failure usually develops within 24 hours and may be life-threatening.

Mercuric salts are corrosive and nephrotoxic. Salivation, metallic taste, abdominal pain, seizures, proteinuria, nephrotic syndrome (oliguria and anuria) may occur. Circulatory collapse, bloody diarrhea, and acute renal failure have been reported following peritoneal lavage with mercuric chloride.

Toxicity from organic mercurials may be delayed up to weeks following exposure. Nausea, vomiting, abdominal pain, diarrhea, paresthesias of the lips and mouth and lethargy may occur. Various organomercurials are known human teratogens and can induce severe neurological defects in the unborn.

The brain is the critical organ for chronic mercury poisoning. Tremor and psychological changes including increased irritability and sensitivity, xenophobia, insomnia, hallucinations, and mania may occur. Eventually there is spongeous degeneration of the brain with loss of many higher functions.

When mercury poisoning is suspected in critically ill patients, chelation therapy should be started regardless of the form of mercury causing toxicity.

POTENTIAL HEALTH HAZARDS - EMERGENCY RESPONSE GUIDEBOOK, GUIDE 151 (ERG, 2004)

Highly toxic, may be fatal if inhaled, swallowed or absorbed through skin.
Avoid any skin contact.
Effects of contact or inhalation may be delayed.
Fire may produce irritating, corrosive and/or toxic gases.
Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution.

ACUTE CLINICAL EFFECTS

Phenylmercuric salts (acetate, nitrate) in concentrations of 0.1 percent and greater are primary irritants. Initially erythema and burning appear, followed by vesicles within 48 hours (Morris, 1960; Koby, 1972). Methoxyethylmercuric acetate would be expected to act in a similar manner. METHOXYMETHYLMERCURIC ACETATE, a closely related compound, was systemically absorbed through the skin of one female worker (Jovicic, 1968).

Mercury compounds can be absorbed by all routes of exposure (HSDB , 1993). Nausea, vomiting, and diarrhea may occur from ingestion or inhalation of inorganic mercury salts (Clayton & Clayton, 1981).

Mercury is an insidious poison which can produce permanent effects in the central and peripheral nervous systems. The onset of signs and symptoms can be immediate or delayed. Permanent effects can occur from acute exposure.

Sudden and profound circulatory collapse with tachycardia, hypotension, and peripheral vasoconstriction can occur from acute inorganic mercury poisoning. Severe and potentially fatal pulmonary edema can occur from inhalation of mercury vapor (ILO, 1983).

Inorganic mercury salts are corrosive. Ingestion may cause a metallic taste, foul breath, loosening of teeth, burning, and intense salivation.

Mercury crosses the blood-brain barrier (Blum & Manzo, 1985). A neurological syndrome resembling amyotrophic lateral sclerosis (Lou Gehrig disease) can occur, even with acute exposure to mercury and its salts (Adams et al, 1983). The peripheral nervous system effects involve a dying-back distal-peripheral axonopathy, followed by demyelination. General loss of brain function may also occur.

Confusion, hallucinations, irritability, sleep disturbances, ataxia, impairment of memory and speech functions, emotional instability, and stupor may occur in acute mercury poisoning (Morgan, 1989).

A large amount of mercurial salts become localized in the kidney, producing a generalized increase in the permeability of the tubular epithelium. Nephrotic syndrome occurs with oliguria and anuria, sometimes requiring treatment with hemodialysis. Diagnosis should be based on elevated urinary mercury excretion. Renal failure usually develops within 24 hours and is associated with albuminuria, epithelial cell casts, hematuria, glycosuria, and aminoaciduria (Gyrd-Hansen & Helleberg, 1976).

CHRONIC CLINICAL EFFECTS

THE BRAIN IS THE CRITICAL TARGET ORGAN FOR CHRONIC MERCURY POISONING (Clayton & Clayton, 1981). The half-life for mercury in the brain is 10 YEARS, and high levels of mercury may be present in the brain years after cessation of exposure (Blum & Manzo, 1985). CUMULATIVE TOXICITY is a major consideration with chronic exposure.

Mercury poisoning is characterized by PHYSICAL, PSYCHOLOGICAL, and NEUROLOGICAL effects. Tremor first appears in the eyelids and progresses to the extremities. The tremor from chronic mercury poisoning resembles that of Parkinson's disease (Ohlson & Hogstedt, 1981).

Chronic exposure to airborne levels of approximately 0.026 mg/m(3) has been associated with subclinical tremor (Fawer et al, 1983). Ataxia may also occur (O'Donoghue, 1985).

Peripheral neuropathy of the mixed sensory and motor type with continued degeneration of nerve fibers even after cessation of exposure has been associated with chronic exposure to mercury and its salts (Blum & Manzo, 1985).

Spongeous degeneration of the brain, accompanied by loss of many higher functions, occurs from chronic exposure to mercury (Clayton & Clayton, 1981). In a NIOSH study, there was a 4.9 millisecond increase in memory time for each 0.1 mg/L of urinary mercury (Langolf, 1981). Impairment of memory becomes more severe with exposure of at least 10 years (Piikivi et al, 1984).

Because mercury accumulates with chronic exposure, similar circulatory effects to those that may occur with acute exposure including sudden and profound circulatory collapse with tachycardia, hypotension, and peripheral vasoconstriction may occur with chronic exposure.

In the eye, brown deposits of mercury in the lens cause opacity (Clayton & Clayton, 1981). Narrowing of the visual field and an increase in the size of the blind spot are ophthalmic signs of chronic exposure to mercury and its inorganic salts (Gmyrya et al, 1970). Excessive salivation and gingivitis occur with chronic poisoning from inorganic mercurials (HSDB , 1993).

Feeding studies in pigs indicated that renal impairment is a major effect of the related compound methoxymethylmercury acetate (Gyrd-Hansen & Helleberg, 1976). In this respect, its effects may be indistinguishable from those of inorganic mercury. Chronic exposure can lead to impairment of kidney function, resulting in poor correlation between urinary mercury levels and body burden.

Hypersensitivity reactions may develop to mercurial compounds. Patch testing with a 0.05 percent concentration is recommended (Fisher, 1972). Acrodynia, a particular form of hypersensitization to mercurials, has been seen in children aged 4 months to 4 years. This reaction involves generalized body rash, chills, profuse perspiration, desquamation of the palms and soles, swelling of the cheeks, nose, hands, and feet, photophobia, irritability, and sleeplessness (HSDB , 1993).

A particular psychiatric syndrome called MERCURIAL ERETHISM is one of the hallmarks of chronic mercury poisoning (Finkel, 1983). The early stages involve short-term memory loss (Smith, 1983) and personality changes of increased irritability, xenophobia, insomnia, impaired concentration, and apathy. Severe cases manifest hallucinations and mania (O'Donoghue, 1985). Women may be more sensitive than men to the psychological effects of mercury (Ross & Sholito, 1983).

-FIRST AID

FIRST AID AND PREHOSPITAL TREATMENT

Dermal exposures should be washed off with soap and water. No other prehospital decontamination is indicated. Organic mercury spills should be contained and cleaned by qualified hazardous material abatement crews.

-MEDICAL TREATMENT

LIFE SUPPORT

Support respiratory and cardiovascular function.

SUMMARY

FIRST AID - EMERGENCY RESPONSE GUIDEBOOK, GUIDE 151 (ERG, 2004)

Move victim to fresh air.
Call 911 or emergency medical service.
Give artificial respiration if victim is not breathing.
Do not use mouth-to-mouth method if victim ingested or inhaled the substance;give artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device.
Administer oxygen if breathing is difficult.
Remove and isolate contaminated clothing and shoes.
In case of contact with substance, immediately flush skin or eyes with running water for at least 20 minutes.
For minor skin contact, avoid spreading material on unaffected skin.
Keep victim warm and quiet.
Effects of exposure (inhalation, ingestion or skin contact) to substance may be delayed.
Ensure that medical personnel are aware of the material(s) involved and take precautions to protect themselves.

FIRST AID

SUMMARY: Dermal exposures should be washed off with soap and water. No other prehospital decontamination is indicated. Organic mercury spills should be contained and cleaned by qualified hazardous material abatement crews.
INHALATION EXPOSURE

INHALATION: Move patient to fresh air. Monitor for respiratory distress. If cough or difficulty breathing develops, evaluate for respiratory tract irritation, bronchitis, or pneumonitis. Administer oxygen and assist ventilation as required. Treat bronchospasm with an inhaled beta2-adrenergic agonist. Consider systemic corticosteroids in patients with significant bronchospasm.

EYE EXPOSURE

DECONTAMINATION: Remove contact lenses and irrigate exposed eyes with copious amounts of room temperature 0.9% saline or water for at least 15 minutes. If irritation, pain, swelling, lacrimation, or photophobia persist after 15 minutes of irrigation, the patient should be seen in a healthcare facility.
Treatment should include recommendations listed in the INHALATION EXPOSURE section when appropriate.

-RANGE OF TOXICITY

MINIMUM LETHAL EXPOSURE

ACUTE

The average lethal dose for organic mercurial compounds is about 100 mg (Baselt, 1988).

MAXIMUM TOLERATED EXPOSURE

GENERAL/SUMMARY

There is no adequate test to detect signs of mercury poisoning while at the subclinical (ie, reversible) stage (Cherian et al, 1978).
Proteinuria may be evident before neurological effects appear (IOHS, 1982; Schuckmann, 1979).
Neuropsychological testing, when compared with a given individual's baseline or pre-exposure results, may be useful in detecting subtle signs of mercury poisoning (Chaffin et al, 1973).
Generally the correlation between urinary levels of mercury in individuals and exposure is poor (O'Donaghue, 1985).
Better correlation has been seen in analyses of groups (Blum & Manzo, 1985). One study found that 50 mcg/m(3) exposure to mercury correlated with urinary levels of 50 mcg/L (Blum & Manzo, 1985).

ROUTE OF EXPOSURE

Atmospheric levels exceeding 0.01 milligram/cubic meter organic mercury may be toxic. Maximum tolerated oral concentrations are unknown; acute toxicity occurred following absorption of 60 to 90 milliliters of mercurial fungicides.
The daily "safe" limit for methylmercury contaminated fish is 0.03 milligram.
A single acute ingestion of 45 milligrams of methylmercury resulted in whole blood levels of 1930 and 1007 nanograms/milliliter 2 and 24 hours after ingestion, but did not result in symptoms of toxicity (Lund et al, 1984).

Carcinogenicity Ratings for CAS151-38-2 :

ACGIH (American Conference of Governmental Industrial Hygienists, 2010): Not Listed
EPA (U.S. Environmental Protection Agency, 2011): Not Listed
IARC (International Agency for Research on Cancer (IARC), 2016; International Agency for Research on Cancer, 2015; IARC Working Group on the Evaluation of Carcinogenic Risks to Humans, 2010; IARC Working Group on the Evaluation of Carcinogenic Risks to Humans, 2010a; IARC Working Group on the Evaluation of Carcinogenic Risks to Humans, 2008; IARC Working Group on the Evaluation of Carcinogenic Risks to Humans, 2007; IARC Working Group on the Evaluation of Carcinogenic Risks to Humans, 2006; IARC, 2004): Not Listed
NIOSH (National Institute for Occupational Safety and Health, 2007): Not Listed
MAK (DFG, 2002): Not Listed
NTP (U.S. Department of Health and Human Services, Public Health Service, National Toxicology Project ): Not Listed

TOXICITY AND RISK ASSESSMENT VALUES

EPA IRIS

EPA Risk Assessment Values for CAS151-38-2 (U.S. Environmental Protection Agency, 2011):

Not Listed

TOXICITY VALUES

References: RTECS, 1997
- LD50- (ORAL)MOUSE:
- LD50- (ORAL)RAT:

-STANDARDS AND LABELS

WORKPLACE STANDARDS

ACGIH TLV Values for CAS151-38-2 (American Conference of Governmental Industrial Hygienists, 2010):

Not Listed

AIHA WEEL Values for CAS151-38-2 (AIHA, 2006):

Not Listed

NIOSH REL and IDLH Values for CAS151-38-2 (National Institute for Occupational Safety and Health, 2007):

Not Listed

OSHA PEL Values for CAS151-38-2 (U.S. Occupational Safety, and Health Administration (OSHA), 2010):

Not Listed

OSHA List of Highly Hazardous Chemicals, Toxics, and Reactives for CAS151-38-2 (U.S. Occupational Safety and Health Administration, 2010):

Not Listed

ENVIRONMENTAL STANDARDS

EPA CERCLA, Hazardous Substances and Reportable Quantities for CAS151-38-2 (U.S. Environmental Protection Agency, 2010):

Not Listed

EPA CERCLA, Hazardous Substances and Reportable Quantities, Radionuclides for CAS151-38-2 (U.S. Environmental Protection Agency, 2010):

Not Listed

EPA RCRA Hazardous Waste Number for CAS151-38-2 (U.S. Environmental Protection Agency, 2010b):

Not Listed
Editor's Note: The D, F, and K series waste numbers and Appendix VIII to Part 261 -- Hazardous Constituents were not included. Please refer to 40 CFR Part 261.

EPA SARA Title III, Extremely Hazardous Substance List for CAS151-38-2 (U.S. Environmental Protection Agency, 2010):

Listed as: Methoxyethylmercuric Acetate
Reportable Quantity, in pounds: 500

Only the statutory or final RQ is shown. For more information, see 40 CFR table 302.4.

Threshold Planning Quantity, in pounds:

500/10,000
Amount necessary to be covered by this standard. See 40 CFR 355.30.

Note(s): Not Listed

EPA SARA Title III, Community Right-to-Know for CAS151-38-2 (40 CFR 372.65, 2006; 40 CFR 372.28, 2006):

Not Listed

DOT List of Marine Pollutants for CAS151-38-2 (49 CFR 172.101 - App. B, 2005):

Not Listed

EPA TSCA Inventory for CAS151-38-2 (EPA, 2005):

Not Listed

SHIPPING REGULATIONS

SURFACE

DOT -- Table of Hazardous Materials and Special Provisions (49 CFR 172.101, 2005):

Not Listed

ICAO International Shipping Name (ICAO, 2002):

Not Listed

LABELS

NFPA

NFPA Hazard Ratings for CAS151-38-2 (NFPA, 2002):

Not Listed

-PERSONAL PROTECTION

SUMMARY

RECOMMENDED PROTECTIVE CLOTHING - EMERGENCY RESPONSE GUIDEBOOK, GUIDE 151 (ERG, 2004)

Wear positive pressure self-contained breathing apparatus (SCBA).
Wear chemical protective clothing that is specifically recommended by the manufacturer. It may provide little or no thermal protection.
Structural firefighters' protective clothing provides limited protection in fire situations ONLY; it is not effective in spill situations where direct contact with the substance is possible.

Wear full protective clothing when working in the vicinity of spills or leaks or when fighting fires (AAR, 1987).

Alkyl mercury compounds tend to cause burning and rashes with dermal contact and eye contact (Clayton & Clayton, 1981).

Wear appropriate clothing to prevent any possibility of skin contact. Wear eye protection to prevent any possibility of eye contact (Sittig, 1985).

RESPIRATORY PROTECTION

Wear a self-contained positive pressure breathing apparatus when working in the vicinity of spills or leaks or when fighting fires (AAR, 1987).

Refer to "Recommendations for respirator selection" in the NIOSH Pocket Guide to Chemical Hazards on TOMES Plus(R) for respirator information.

PROTECTIVE CLOTHING

CHEMICAL PROTECTIVE CLOTHING. Search results for CAS 151-38-2.

Specific recommendations and test data for this chemical were not found in the available manufacturers' product literature. A complete list of consulted manufacturers and references is presented below.

-PHYSICAL HAZARDS

FIRE HAZARD

SUMMARY

Editor's Note: This material is not listed in the Emergency Response Guidebook. Based on the material's physical and chemical properties, toxicity, or chemical group, a guide has been assigned. For additional technical information, contact one of the emergency response telephone numbers listed under Public Safety Measures.
POTENTIAL FIRE OR EXPLOSION HAZARDS - EMERGENCY RESPONSE GUIDEBOOK, GUIDE 151 (ERG, 2004)
- Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes.
- Containers may explode when heated.
- Runoff may pollute waterways.
When heated to decomposition, methoxyethylmercuric acetate releases highly toxic fumes of mercury and mercury oxide (Sax & Lewis, 1989).

FLAMMABILITY CLASSIFICATION

NFPA Flammability Rating for CAS151-38-2 (NFPA, 2002):

Not Listed

FIRE CONTROL/EXTINGUISHING AGENTS

SMALL FIRE PRECAUTIONS - EMERGENCY RESPONSE GUIDEBOOK, GUIDE 151 (ERG, 2004)

Dry chemical, CO2 or water spray.

LARGE FIRE PRECAUTIONS - EMERGENCY RESPONSE GUIDEBOOK, GUIDE 151 (ERG, 2004)

Water spray, fog or regular foam.
Move containers from fire area if you can do it without risk.
Dike fire control water for later disposal; do not scatter the material.
Use water spray or fog; do not use straight streams.

TANK OR CAR/TRAILER LOAD FIRE PRECAUTIONS - EMERGENCY RESPONSE GUIDEBOOK, GUIDE 151 (ERG, 2004)

Fight fire from maximum distance or use unmanned hose holders or monitor nozzles.
Do not get water inside containers.
Cool containers with flooding quantities of water until well after fire is out.
Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank.
ALWAYS stay away from tanks engulfed in fire.
For massive fire, use unmanned hose holders or monitor nozzles; if this is impossible, withdraw from area and let fire burn.

NFPA Extinguishing Methods for CAS151-38-2 (NFPA, 2002):

Not Listed

Choose an extinguishing agent suitable for fires in surrounding material (AAR, 1987).

Water may be used in flooding quantities as fog (AAR, 1987).

COMBUSTION TOXICITY

When heated to decomposition, methoxyethylmercuric acetate releases highly toxic fumes of mercury and mercury oxide (Sax & Lewis, 1989).

DUST/VAPOR HAZARD

When heated to decomposition, methoxyethylmercuric acetate releases highly toxic fumes of mercury and mercury oxide (Sax & Lewis, 1989).

REACTIVITY HAZARD

When heated to decomposition, methoxyethylmercuric acetate releases highly toxic fumes of mercury (Lewis, 1996).

EVACUATION PROCEDURES

SUMMARY

Editor's Note: This material is not listed in the Table of Initial Isolation and Protective Action Distances.

SPILL - PUBLIC SAFETY EVACUATION DISTANCES - EMERGENCY RESPONSE GUIDEBOOK, GUIDE 151 (ERG, 2004)

Increase, in the downwind direction, as necessary, the isolation distance of at least 25 to 50 meters (80 to 160 feet) in all directions.

FIRE - PUBLIC SAFETY EVACUATION DISTANCES - EMERGENCY RESPONSE GUIDEBOOK, GUIDE 151 (ERG, 2004)

If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions.

PUBLIC SAFETY MEASURES - EMERGENCY RESPONSE GUIDEBOOK, GUIDE 151 (ERG, 2004)

CALL Emergency Response Telephone Number on Shipping Paper first. If Shipping Paper not available or no answer, refer to appropriate telephone number:

MEXICO:

SETIQ:

01-800-00-214-00 in the Mexican Republic;
For calls originating in Mexico City and the Metropolitan Area: 5559-1588;
For calls originating elsewhere, call: 011-52-555-559-1588.

CENACOM:

01-800-00-413-00 in the Mexican Republic;
For calls originating in Mexico City and the Metropolitan Area: 5550-1496, 5550-1552, 5550-1485, or 5550-4885;
For calls originating elsewhere, call: 011-52-555-550-1496, or 011-52-555-550-1552; 011-52-555-550-1485, or 011-52-555-550-4885.

ARGENTINA:

CIQUIME:

0-800-222-2933 in the Republic of Argentina;
For calls originating elsewhere, call: +54-11-4613-1100.

BRAZIL:

PRÓ-QUÍMICA:

0-800-118270 (Toll-free in Brazil);
For calls originating elsewhere, call: +55-11-232-1144 (Collect calls are accepted).

COLUMBIA:

CISPROQUIM:

01-800-091-6012 in Colombia;
For calls originating in Bogotá, Colombia, call: 288-6012;
For calls originating elsewhere, call: 011-57-1-288-6012.

CANADA:

CANUTEC:

613-996-6666 (Collect calls are accepted);
*666 cellular (in Canada only).

UNITED STATES:

CHEMTREC®:

1-800-424-9300 (Toll-free in the U.S., Canada, and the U.S. Virgin Islands);
703-527-3887 for calls originating elsewhere (Collect calls are accepted).

CHEM-TEL, INC.:

1-800-255-3924 (Toll-free in the U.S., Canada, and the U.S. Virgin Islands);
813-248-0585 for calls originating elsewhere (Collect calls are accepted).

INFOTRAC:

1-800-535-5053 (Toll-free in the U.S., Canada, and the U.S. Virgin Islands);
352-323-3500 for calls originating elsewhere (Collect calls are accepted).

3E COMPANY:

1-800-451-8346 (Toll-free in the U.S., Canada, and the U.S. Virgin Islands);
760-602-8703 for calls originating elsewhere (Collect calls are accepted).

NATIONAL RESPONSE CENTER (NRC):

1-800-424-8802 - (24 hours) (Toll-free in the U.S., Canada, and the U.S. Virgin Islands);
202-267-2675 for calls in the District of Columbia.

MILITARY SHIPMENTS:

703-697-0218 - Explosives/ammunition incidents (Collect calls are accepted);
1-800-851-8061 - All other dangerous goods incidents.

NATIONWIDE POISON CONTROL CENTER (United States only):

1-800-222-1222 (Toll-free in the U.S.).

For additional details see the section entitled "WHO TO CALL FOR ASSISTANCE" under the ERG Instructions.
As an immediate precautionary measure, isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids.
Keep unauthorized personnel away.
Stay upwind.
Keep out of low areas.

Downwind evacuation should be considered if this material is involved in a fire or if a large discharge has occurred (AAR, 1987).

AIHA ERPG Values for CAS151-38-2 (AIHA, 2006):

Not Listed

DOE TEEL Values for CAS151-38-2 (U.S. Department of Energy, Office of Emergency Management, 2010):

Listed as Methoxyethylmercuric acetate
TEEL-0 (units = mg/m3): 0.0159
TEEL-1 (units = mg/m3): 0.0477
TEEL-2 (units = mg/m3): 3.18
TEEL-3 (units = mg/m3): 3.18
Definitions:

TEEL-0: The threshold concentration below which most people will experience no adverse health effects.
TEEL-1: The airborne concentration (expressed as ppm [parts per million] or mg/m(3) [milligrams per cubic meter]) of a substance above which it is predicted that the general population, including susceptible individuals, could experience notable discomfort, irritation, or certain asymptomatic, nonsensory effects. However, these effects are not disabling and are transient and reversible upon cessation of exposure.
TEEL-2: The airborne concentration (expressed as ppm or mg/m(3)) of a substance above which it is predicted that the general population, including susceptible individuals, could experience irreversible or other serious, long-lasting, adverse health effects or an impaired ability to escape.
TEEL-3: The airborne concentration (expressed as ppm or mg/m(3)) of a substance above which it is predicted that the general population, including susceptible individuals, could experience life-threatening adverse health effects or death.

AEGL Values for CAS151-38-2 (National Research Council, 2010; National Research Council, 2009; National Research Council, 2008; National Research Council, 2007; NRC, 2001; NRC, 2002; NRC, 2003; NRC, 2004; NRC, 2004; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2006; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2007; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2005; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2005; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2007; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2006; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2006; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2006; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2006; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2006; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2006; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2006; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2006; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2006; United States Environmental Protection Agency Office of Pollution Prevention and Toxics, 2006; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2006; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2007; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2007; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2008; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2008; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2007; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2008; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2007; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2008; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2007; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2009; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2009; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2009; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2009; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2009; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2009; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2009; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2009; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2009; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2009; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2009; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2008; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2008; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2008; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2008; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2008; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2008; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2008; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2009; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2008; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2008; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2008; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2009; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2008; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2008; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2008; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2008; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2008; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2008; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2008; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2007; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2006; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2006; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2006; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2007; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2007; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2007; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2007; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2007; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2005; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2005; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2005; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2005; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2005; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2005; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2005; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2005; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2007; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2005; National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances, 2006; 62 FR 58840, 1997; 65 FR 14186, 2000; 65 FR 39264, 2000; 65 FR 77866, 2000; 66 FR 21940, 2001; 67 FR 7164, 2002; 68 FR 42710, 2003; 69 FR 54144, 2004):

Not Listed

NIOSH IDLH Values for CAS151-38-2 (National Institute for Occupational Safety and Health, 2007):

Not Listed

CONTAINMENT/WASTE TREATMENT OPTIONS

SUMMARY

SPILL OR LEAK PRECAUTIONS - EMERGENCY RESPONSE GUIDEBOOK, GUIDE 151 (ERG, 2004)
- Do not touch damaged containers or spilled material unless wearing appropriate protective clothing.
- Stop leak if you can do it without risk.
- Prevent entry into waterways, sewers, basements or confined areas.
- Cover with plastic sheet to prevent spreading.
- Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers.
- DO NOT GET WATER INSIDE CONTAINERS.
RECOMMENDED PROTECTIVE CLOTHING - EMERGENCY RESPONSE GUIDEBOOK, GUIDE 151 (ERG, 2004)
- Wear positive pressure self-contained breathing apparatus (SCBA).
- Wear chemical protective clothing that is specifically recommended by the manufacturer. It may provide little or no thermal protection.
- Structural firefighters' protective clothing provides limited protection in fire situations ONLY; it is not effective in spill situations where direct contact with the substance is possible.
Water spray may be used to reduce or knock down vapors (AAR, 1987).

SMALL LEAK/SPILL

Isolate and ventilate the area. Keep sources of fire away. Wear rubber or neoprene gloves and overshoes and an approved respirator. Get fire-fighting equipment ready. Contain any liquid spill around the edge and absorb with Zorb-All (R), soil, sweeping compound, sawdust, dry sand or similar material. Dispose of absorbed or dry material in disposable containers (Ford, 1989; EPA, 1975b).

LARGE LEAK/SPILL

Isolate and ventilate the area. Keep sources of fire away. Wear rubber or neoprene gloves and overshoes and approved personal protection equipment. Get fire-fighting equipment ready (Ford, 1989).
In general it would be preferable to detoxify spilled material before absorbing for disposal whenever possible.

-ENVIRONMENTAL HAZARD MANAGEMENT

POLLUTION HAZARD

No information found at the time of this review.

ENVIRONMENTAL FATE AND KINETICS

OTHER

OTHER
- No data were available at the time of this review.

ENVIRONMENTAL TOXICITY

No data were available at the time of this review.

-PHYSICAL/CHEMICAL PROPERTIES

MOLECULAR WEIGHT

318.74 (Lewis, 1996)

DESCRIPTION/PHYSICAL STATE

Crystals or needles (Lewis, 1996)

No information found at the time of this review.

SOLUBILITY

IN WATER

Soluble in water (EPA, 1985) HSDB, 1997)

IN ORGANIC SOLVENTS

No data were available, at the time of this review, on the solubility of methoxyethylmercuric acetate in organic solvents.

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METHOXYETHYLMERCURIC ACETATE

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